Struktur‐Wirkungs‐Beziehungen von Auxinen aus theoretischen Konformationsuntersuchungen und molekularen elektrostatischen Potentialen
- 1 May 1988
- journal article
- research article
- Published by Wiley in Zeitschrift für Chemie
- Vol. 28 (5) , 174-181
- https://doi.org/10.1002/zfch.19880280505
Abstract
New aspects of structure‐activity relationships of auxins were found by theoretical investigations of conformations and molecular electrostatic potentials. The conformation of an active compound is characterized by the formation of an intramolecular hydrogen bond between the side‐chain and the π‐electronic system of the ring part. The molecular electrostatic potentials of active molecules possess a characteristic structure different from that of inactive compounds. Even the explanation of the different behaviour in auxin action of optically active compounds is possible.Keywords
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