Ruthenium-Bisimine: A New Catalytic Precursor for Regioselective Allylic Alkylation
- 7 February 2003
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 2003 (3) , 0408-0410
- https://doi.org/10.1055/s-2003-37120
Abstract
New complexes [Cp*Ru(bisimine)Cl] are active catalysts for the regioselective alkylation of allylic carbonates by soft carbonucleophiles, in favour of the branched isomers. The catalysts can be conveniently prepared in situ from [Cp*Ru(cod)Cl] and a bulky aromatic bisimine.Keywords
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