Adducts of oxovanadium(IV) dithiocarbamates

Publisher Website
Google Scholar
Abstract
Pyridine and 4-methylpyridine adducts of oxovanadium(IV) dithiocarbamates have been isolated and characterized as solids. It has been shown that the addenda can be removed under mild conditions with concomitant regeneration of the parent dithiocarbamate (DTC) complexes. Attempts to isolate dimethyl-sulfoxide adducts have not been successful, although spectral evidence suggests that adducts are formed in solution. A qualitative rationalization of the molecular orbital ordering and electronic spectral properties of the adducts is presented.

This publication has 0 references indexed in Scilit: