Two-electron transfer catalysis of carbon monoxide exchange¹with a ligand in hexacarbonyldi-iron compounds [(µ-RS)₂Fe₂(CO)₆]

1 January 1988

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 14,p. 968-970
https://doi.org/10.1039/c39880000968

Abstract

Two-electron reduction of [(µ-RS)₂Fe₂(CO)₆](R = alkyl) leads to labile dianionic species which lose CO and decay or, in the presence of a ligand (L) such as P(OMe)₃, are involved in a chain reaction affording successively [(µ-RS)₂Fe₂(CO)₅L] and [(µ-RS)₂Fe₂(CO)₄L₂].

Keywords

IRON
ELECTRON TRANSFER
CARBON MONOXIDE

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Two-electron transfer catalysis of carbon monoxide exchange1with a ligand in hexacarbonyldi-iron compounds [(µ-RS)2Fe2(CO)6]

Abstract

Keywords

Two-electron transfer catalysis of carbon monoxide exchange¹with a ligand in hexacarbonyldi-iron compounds [(µ-RS)₂Fe₂(CO)₆]