Fluorescence of aqueous sodium salicylate. Solutions under excitation by ionizing radiations
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 67, 1678-1689
- https://doi.org/10.1039/tf9716701678
Abstract
The equations derived in the expanding sphere model1 are applied to the experimental results on the fluorescence from aqueous salicylate solutions under X-irradiation. The results fit the theory well over a wide concentration range and their deviation from the behaviour of the same system under u.-v. irradiation agrees quantitatively with a mechanism involving the non-homogeneous quenching by radiation-induced radicals of solute molecules excited by the same ionizing radiations.Keywords
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