Electroreflectance Spectrum of CdTe 1-xSx Mixed Crystal Layer in CdS/CdTe Thin-Film Solar Cell

Abstract
The electroreflectance (ER) spectrum of the CdS/CdTe thin-film solar cell has been studied in conjunction with the results on the atomic element depth profile. The ER spectrum occurs with three spectral components with optical transition energies of 1.44 eV, 1.47 eV and 1.49 eV at 293 K. The mixed crystal layer of CdTe1-x Sx, ∼2 µm thick (x>0.004), extends from the CdS/CdTe metallurgical interface into the CdTe layer, and the np junction locates in the mixed crystal layer. The dominant 1.47-eV ER component is assigned to the band gap of the mixed crystal layer of CdTe0.95S0.05 at around the np junction.@keyword CdTe1- x S x , CdS/CdTe solar cell, mixed crystal, electroreflectance, SIMS, np junction