Electron Spin Resonance of the Aromatic-Alkali Metal System
Open Access
- 1 August 1963
- journal article
- Published by Oxford University Press (OUP) in Progress of Theoretical Physics
- Vol. 30 (2) , 162-169
- https://doi.org/10.1143/ptp.30.162
Abstract
A theoretical investigation is made to interpret the Na hyperfine splittings in electron spin resonance of the aromatic-Na system in solution. In calculating the odd electron density on the Na nucleus, one assumes the charge transfer mechanism that the odd electron, in the first approximation, accommodated in the π-molecular orbital of the aromatic migrates to the Na atom through overlapping between orbitals. The result obtained shows fairly good agreement with observation.Keywords
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