Carbon–carbon bond formation through olefin–methylcarbyne linkage at a diruthenium centre: X-ray crystal structure of [Ru2(CO)(µ-CO){µ-η1,η3-C(Me)C(Me)CH2}(η-C5H5)2]
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 537-538
- https://doi.org/10.1039/c39810000537
Abstract
Reaction of [Ru2(CO)2(µ-CO)(µ-CMe)(η-C5H5)2]+ with RCHCH2(R = H or Me) under u.v. radiation provides [Ru2(CO)(µ-CO){µ-η1,η3-C(Me)C(R)-CH2}(η-C5H5)2] which, for RH, may also be obtained by treatment of [Ru2(CO)(C2H4)(µ-CO)2(η-C5H5)2] with MeLi, HBF4 successively; the structure of [Ru2(CO)(µ-CO){µ-η1,η3-C(Me)C(Me)CH2}(η-C5H5)2] has been determined by X-ray diffraction.Keywords
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