Implications of a Transition State in a Diels–Alder Reaction in Supercritical Carbon Dioxide
- 1 June 1994
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 67 (6) , 1734-1736
- https://doi.org/10.1246/bcsj.67.1734
Abstract
For the Diels–Alder reaction between isoprene and methyl acrylate in supercritical carbon dioxide at 323 K, the solubility parameter of the activated complex was determined as a function of the pressure, ranging from 7 to 20 MPa, in order to study the nature of the complex and the effect of the solvent on the reaction. The relation between the solubility parameter and the ET(30)-scale was examined as well.Keywords
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