Insights into the elimination of HCHO from the clusters [Mn(CO)m(COOMe)]− (Mn = Ru6C, m = 16; Mn = Rh6, m = 15) provided by electrospray mass spectrometry †

Abstract
Loss of formaldehyde in the electrospray ionisation fragmentation process of methoxylated hexanuclear carbonyl clusters can be correlated to their macroscopic chemical properties.

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