Synthesis and Electrical Conductivities of Some Metal Complexes with the Extended Dithiolato Ligand Having a C8S8 Skeleton
- 1 June 1996
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals
- Vol. 284 (1) , 301-305
- https://doi.org/10.1080/10587259608037932
Abstract
The new dithiolato ligand with an extended π-electron system, CgH4S8 2-(2-[(4,5-ethylenedithio)-1,3-dithiole-2-ylidene]-1,3-dithiole-4,5-dithiolate) was synthesized and [NBun 4][Au(C8H4S8)2] and Pt(C8H4S8)-(SEt2)2 prepared. Redox potentials of these complexes were determined. Their oxidized species and Na1.5[Ni(C8H4S8)2] exhibit electrical conductivities of 0.06-17 S cm−1 at room temperature for compacted pellets.This publication has 10 references indexed in Scilit:
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