Preparation, thermal stability and crystal structure of a new ruthenium(V) oxide containing peroxide ions: Ba5Ru2O9(O2). Structural relationships to thehexagonal-type perovskite
- 1 January 1997
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 7 (9) , 1911-1915
- https://doi.org/10.1039/a701085k
Abstract
The compound Ba5Ru2O11 has been synthesized by solid state reactions at 980 °C and 1 atm oxygen pressure. The crystal structure has been determined on a single crystal (R1=0.027, wR2=0.058). The symmetry is hexagonal (P63 /mmc) with the cell parameters a=5.9470(5) Å, c=18.0428(10) Å, Z=2. Perpendicular to the c-axKeywords
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