Metathesis polymerization of 7-oxa-2,3-bismethoxycarbonylbicyclo[2.2.1]hepta-2,5-diene: synthesis of novel conjugated polyenes
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 119-121
- https://doi.org/10.1039/c39900000119
Abstract
Novel high-molecular-weight polymers are readily made by the alkene metathesis reaction using 7-oxa-2,3-bismethoxycarbonylbicyclo[2.2.1]hepta-2,5-diene as the monomer and Ru and Os chlorides as catalysts; these polymers are readily dehydrogenated using dichlorodicyanobenzoquinone to afford novel purple–red conjugated polyenes.Keywords
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