Apparent Five-Coordinate Metal Complexes: Evidence for Trifunctional Bridge Bonding with the 3-Cyano-2,4-Pentanedionate Ligand in the Trichloro(3-Cyano-2,4-Pentanedionato) Complexes of Tin(IV) and Titanium(IV)
- 1 August 1973
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 3 (1) , 119-121
- https://doi.org/10.1080/00958977308073796
Abstract
Sir: We wish to report evidence for an oligomeric structure in trichloro(3-cyano-2,4-pentanedionato) titanium(IV), C13TiL, and trichloro(3-cyano-2,4-pentanedionato)tin(IV), C13SnL. Evidence is presented that oligomerization is accomplished by a novel bridging interaction involving the planar trifunctional 3-cyano-2,4-pentanedionate anion.Keywords
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