Transylidations of Stable Sulfonium Ylids
- 1 September 1973
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 46 (9) , 2845-2849
- https://doi.org/10.1246/bcsj.46.2845
Abstract
In the presence of a dialkoxy disulfide, sulfonium bis(methoxycarbonyl)methylids underwent transylidation with a dialkyl sulfide or pyridine at 35 °C. Thiocyanogen and benzoyl disulfide showed a similar catalytic effect. The kinetics of this reaction were investigated, and its mechanism was discussed.This publication has 10 references indexed in Scilit:
- Reactions of dimethyl diazomalonate with divalent sulfidesThe Journal of Organic Chemistry, 1972
- New and useful sulfur ylide: thetin anionsThe Journal of Organic Chemistry, 1970
- Chemistry of Ylides. XIX. .beta.-Carbonyl sulfonium ylidesThe Journal of Organic Chemistry, 1969
- Ethyl (dimethylsulfuranylidene)acetate. IV. Miscellaneous reactionsThe Journal of Organic Chemistry, 1968
- Nucleophilic reactivity constants toward methyl iodide and trans-dichlorodi(pyridine)platinum(II)Journal of the American Chemical Society, 1968
- Cyclopropanes from reactions of ethyl dimethylsulfuranylideneacetate with .alpha.,.beta.-unsaturated compoundsThe Journal of Organic Chemistry, 1967
- Dimethylsulfonium PhenacylideJournal of the American Chemical Society, 1967
- Structures and Reactions of Certain Sulfur-YlidesNippon kagaku zassi, 1967
- Organic Esters of Bivalent Sulfur. I. Dialkoxy DisulfidesThe Journal of Organic Chemistry, 1965
- Steric Effects in Displacement Reactions. II. The Rates of Reaction of Alkyl Iodide s with the Monoalkylpyridines. Steric Strain in the Activated ComplexJournal of the American Chemical Society, 1955