Phosphorus-31 and oxygen-17 n.m.r. evidence of trapped electrons in reduced 18-molybdodiphosphate(V), P2Mo18O62 8?
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 644-646
- https://doi.org/10.1039/c39800000644
Abstract
Reduction of the P2Mo18O62 6– anion by two electrons results in the mixed valence form and, by using 31P and 17O n.m.r. high resolution spectra, these electrons are deduced to be firmly trapped by two adjacent molybdenum atoms located in both half-units of the anion.Keywords
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