Amino Acid Esters: Versatile Chiral Auxiliary Groups for the Asymmetric Synthesis of Nitrogen Heterocycles
- 1 February 1995
- journal article
- account
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1995 (02) , 133-141
- https://doi.org/10.1055/s-1995-4882
Abstract
The development of amino acid esters as chiral auxiliary groups for the asymmetric construction of N-heterocycles by means of aza Diels-Alder reactions, Mannich reactions, Pictet-Spengler reactions and 1,3-dipolar cycloadditions is described. Also their application in the steric steering of carbo Diels-Alder reactions, radicalic transformations and enantioselective nucleophilic additions to carbonyl groups is highlighted.Keywords
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