(μ-Alkoxo)diiron(II,II) Complexes of N,N,N′,N′-Tetrakis(2-(6-methylpyridyl)methyl)-1,3-diaminopropane-2-olate and the Reversible Formation of the O2-Adducts
- 1 January 1992
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 21 (1) , 91-94
- https://doi.org/10.1246/cl.1992.91
Abstract
(μ-Alkoxo)(μ-carboxylato)diiron(II,II) complexes with hindered dinucleating ligand were synthesized and the structure of μ-benzoato derivative was determined by X-ray analysis. The complexes showed reversible oxygenation in acetonitrile and dichloromethane. Resonance Raman spectra of these species demonstrated a possibility of unsymmetrical μ-η1-η1′ binding of the oxygen toward the diiron centers.This publication has 9 references indexed in Scilit:
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