Wurtz-type Coupling Reaction of Pseudo-pentacoordinate Halodisilanes Using Magnesium: Enhanced Reactivity of the Silicon-Halogen Bond by Intramolecular Amine-coordination to Silicon
- 1 April 1999
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 28 (4) , 335-336
- https://doi.org/10.1246/cl.1999.335
Abstract
A 2,3-bis(pseudo-pentacoordinate) tetrasilane was obtained by the reductive dimerization of 1-[8-(dimethylamino)-1-naphthyl]-1-chlorodisilane using magnesium, and also from the analogous 1-fluorodisilane using a mixture of magnesium and magnesium bromide.Keywords
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