The elimination of carbon monoxide from acid derivatives. Part III. Planar carbonium ions as necessary intermediates
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- p. 2548-2554
- https://doi.org/10.1039/j39680002548
Abstract
Elimination of carbon monoxide from acid chlorides by the Friedel-Crafts reaction is precluded if the resulting carbonium ions are restricted to non-planar geometry by bicyclic or other structures with a rigid molecular framework. In such cases the normal ketones are obtained.Keywords
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