Autoxidation of 4-alkyl-2,6-di-t-butylphenols with di-(3-salicylideneaminopropyl)aminecobalt(II) catalyst

1 January 1970

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications

No. 3,p. 163-164
https://doi.org/10.1039/c29700000163

Abstract

Autoxidation of 4-alkyl-2,6-di-t-butylphenols (III) with di-(3-salicylideneaminopropyl)aminecobalt(II) catalyst in methanol gives the corresponding quinols, 4-alkyl-2,6-di-t-butyl-4-hydroxycyclohexa-2,5-dienones (IV), which are formed via the corresponding hydroperoxides (V).

Keywords

ALKYL
BUTYLPHENOLS
CATALYST AUTOXIDATION
CORRESPONDING HYDROPEROXIDES
CORRESPONDING QUINOLS
III
DIENONES

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