Paramagnetic Resonance of Iron Group Elements in Rutile. I. The ${Ti}^{47}$ and ${Ti}^{49}$ hfs Interaction

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6 July 1964

journal article
research article
Published by American Physical Society (APS) in Physical Review B

Vol. 135 (1A) , A144-A148
https://doi.org/10.1103/physrev.135.a144

Abstract

The well-resolved structure of the electron spin resonance (ESR) of

V^{4 +}

and

{Mn}^{4 +}

in rutile (Ti

O_{2}

) is interpreted in terms of the hfs interaction of the

{Ti}^{47}

and

{Ti}^{49}

ions which occupy the nearest sites along the crystalline

c

axis. The absence of such structure in the cases of

{Cr}^{3 +}

and

{Mn}^{3 +}

is discussed in simple terms.

Keywords

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