Formation of 2 : 1 complexes between alkylammonium cations and diaza crown ethers
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1065-1066
- https://doi.org/10.1039/c39790001065
Abstract
The diaza-24-crown-8 derivative (2) forms a 2 : 1 complex with benzylammonium thiocyanate in deuteriomethylene chloride solution; under similar conditions the diaza-24-crown-6 derivative (3) forms 1 : 1 complexes with primary alkylammonium thiocyanates but a crystalline complex of (3) with benzylammonium thiocyanate is shown by X-ray analysis to be a 2 : 1 complex.Keywords
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