Evidence for an Equilibrium between an N-heterocyclic Carbene and Its Dimer in Solution
Top Cited Papers
- 4 February 2000
- journal article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 39 (3) , 541-544
- https://doi.org/10.1002/(sici)1521-3773(20000204)39:3<541::aid-anie541>3.0.co;2-b
Abstract
Evidence for the Wanzlick equilibrium between carbene 1 and dibenzotetraazafulvalene (1)(2) at ambient temperature has been found (see scheme). Enetetramines of type (1)(2) can also be cleaved by coordinatively unsaturated transition metal compounds to form dicarbene complexes.Keywords
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