Binuclear macrocyclic copper(II) complexes as receptors for small bridging ligands: X-ray crystal and molecular structure of a µ-azido complex
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 481-482
- https://doi.org/10.1039/c39790000481
Abstract
In two binuclear copper(II) complexes of a 30-membered Schiff's base macrocyclic ligand the macrocycle adopts a folded conformation which allows intramolecular linkage of the metal atoms via small bridging ligand (N3 – or OH–); the structure of the µ-azido complex has been solved by X-ray analysis.Keywords
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