Control of interpenetrating copper(i) adamantoid networks: synthesis and structure of {[Cu(bpe)2]BF4}n

Abstract
Lengthening of linking bipyridyl ligands in interlocking copper(I)-heterocycle adamantoid arrays increases the volume of the adamantoid cages and consequently the number of observed interpenetrating networks: factors influencing the observed structures of these interpenetrating complexes are described in the context of the structure of {[Cu-(bpe) 2 ]BF 4 } n [bpe = 1,2-trans-(4-pyridyl)ethene].
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