A synthesis of aryl C-glycosides via polyketides
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 434-436
- https://doi.org/10.1039/c39920000434
Abstract
3,5,9,11-Tetraoxotridecanedioates containing C-glycoside units on the side chain were generated from 1-hydroxy sugars, β-ketoglutarate and acetoacetate; intramolecular condensation of the polyketide compounds gave C-glycosidic naphthalene-1,8-diols regio- and stereo-selectively.Keywords
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