Vibrational spectra of alkali chlorates and nitrites in crystalline and molten states

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Abstract
The infrared and Raman spectra of NaClO3 and NaNO2 are reported in crystalline and molten states. The Raman spectra of melts of LiClO3, KClO3, AgClO3, and KKO2 are also reported. The melts all show well-developed lattice-like vibrations which are quite distinct from the crystalline vibrations both in energy and intensity. The spectra are interpreted on the basis of a lattice-like structure in the melt.

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