Dinuclear dihydrido complexes of iridium(II) of the type [Ir(H)(µ-SBut)(CO)(PR3)]2with single metal–metal bonds
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 518-519
- https://doi.org/10.1039/c39770000518
Abstract
[Ir(µ-SBut)(CO)(PR3)]2(I, R = Me, Ph, NMe2, or OMe) reacts irreversibly with molecular hydrogen to give compounds of the type [Ir(H)(µ-SBut)(CO)(PR3)]2(II); 31P and 1H n.m.r. experiments indicate the formation of metal–metal single bonds in these adducts.Keywords
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