Syntheses and Crystal Structures of the New Zinc Phosphonates Zn(O3PCH2P(O)(R)(C6H5))·xH2O, Based on Mixed Phosphonic Acid−Phosphine Oxide Building Blocks
- 1 October 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 36 (21) , 4702-4706
- https://doi.org/10.1021/ic970392j
Abstract
The two new zinc(II) phosphonates Zn(O3PCH2P(O)(C6H5)2) (monoclinic P21/c (No. 14), a = 9.961(2) Å, b = 5.838(1) Å, c = 24.608(5) Å, β = 101.48(3)°, Z = 4) and Zn(O3PCH2P(O)(CH3)(C6H5))·0.67H2O (monoclinic P21/c (No. 14), a = 15.879(5) Å, b = 7.383(2) Å, c = 10.475(3) Å, β = 105.01(5)°, Z = 4) were prepared by reaction of zinc nitrate, (R)(C6H5)P(O)CH2PO3H2 [R = C6H5, CH3], and sodium hydroxide in water in an autoclave. For the first compound, a unidimensional arrangement is observed, while for the second, a layered structure is obtained, in relation to the size of the substituents present on the phosphine oxide moiety.Keywords
This publication has 11 references indexed in Scilit:
- Relationship between Solid-State 31P NMR Parameters and X-ray Structural Data in Some Zinc PhosphonatesChemistry of Materials, 1997
- Synthesis, Characterization, and Amine Intercalation Behavior of Zirconium N-(Phosphonomethyl)iminodiacetic Acid Layered CompoundsChemistry of Materials, 1996
- Structure of Zn(O3PC2H4CO2H)·0.5C6H5NH2and XANES–EXAFS study of the intercalation of amines into Zn(O3PR)·H2O zinc alkylphosphonatesJournal of Materials Chemistry, 1996
- Synthesis, Structure and Reactivity of Some Functionalized Zinc and Copper(II) PhosphonatesInorganic Chemistry, 1995
- Novel structural arrangement for divalent metal phosphonates: synthesis of tert-butylphosphonates and structure of Co[(CH3)3CPO3]·H2OJournal of Materials Chemistry, 1994
- Zirconium Phosphite (3,3′,5,5′‐Tetramethylbiphenyl)diphosphonate, a Microporous, Layered, Inorganic–Organic PolymerAngewandte Chemie International Edition in English, 1993
- Formation of quantum-size semiconductor particles in a layered metal phosphonate host latticeChemistry of Materials, 1991
- An Improvement in the Wittig-Horner Synthesis of 2-Alkenoic AcidsSynthesis, 1978
- Stereospecific alkylation of menthyl phenylphosphinateJournal of the American Chemical Society, 1970
- Synthesis and absolute configuration of optically active phosphine oxides and phosphinatesJournal of the American Chemical Society, 1968