The first volume profile for a host–guest interaction: a variable pressure kinetic study of an inclusion reaction with α-cyclodextrin
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 2787-2788
- https://doi.org/10.1039/cc9960002787
Abstract
The full volume and entropy profiles of the inclusion reaction between α-cyclodextrin and the guest molecule, mordant yellow 7, are constructed from variable pressure and temperature kinetic experiments, showing a two-step mechanism where both steps involve contracted transition states.Keywords
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