Evaporation of Water from Particles in the Aerodynamic Lens Inlet: An Experimental Study

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Abstract
The extremely high particle transmission efficiency of aerodynamic lens inlets resulted in their wide use in aerosol mass spectrometers. One of the consequences of transporting particles from high ambient pressure into the vacuum is that it is accompanied by a rapid drop in relative humidity (RH). Since many atmospheric particles exist in the form of hygroscopic water droplets, a drop in RH may result in a significant loss of water and even a change in phase. How much water is lost in these inlets is presently unknown. Since water loss can affect particle size, transmission efficiency, ionization probability, and mass spectrum, it is imperative to provide definitive experimental data that can serve to guide the field to a reasonable and uniform sampling approach. In this study, we present the results of a number of highly resolved measurements, conducted under well-defined conditions, of water evaporation from a range of particles, during their transport through an aerodynamic lens inlet. We conclude that the only sure way to avoid ambiguities during measurements of aerodynamic diameter in instruments that utilize low-pressure aerodynamic lens inlets is to dry the particles prior to sampling.