Oxygenation reactions of diperoxychromium(VI) oxide etherate (CrO₅–OEt₂). Possible role of singlet oxygen in the isolation of 1,2,3,4-tetraphenyl-5,6-dioxabicyclo[2,2,1]hept-2-en-7-one (tetracyclone endoperoxide)

1 January 1970

journal article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications

No. 22,p. 1550-1551
https://doi.org/10.1039/c29700001550

Abstract

The title epidioxy-ketone was isolated using diperoxychromium(VI) oxide etherate as an oxygenating reagent in a reaction which may involve singlet oxygen as an intermediate.

Keywords

CRO5
DIPEROXYCHROMIUM
ETHERATE
SINGLET OXYGEN
TITLE
TETRAPHENYL
OET2

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Oxygenation reactions of diperoxychromium(VI) oxide etherate (CrO5–OEt2). Possible role of singlet oxygen in the isolation of 1,2,3,4-tetraphenyl-5,6-dioxabicyclo[2,2,1]hept-2-en-7-one (tetracyclone endoperoxide)

Abstract

Keywords

Oxygenation reactions of diperoxychromium(VI) oxide etherate (CrO₅–OEt₂). Possible role of singlet oxygen in the isolation of 1,2,3,4-tetraphenyl-5,6-dioxabicyclo[2,2,1]hept-2-en-7-one (tetracyclone endoperoxide)