Photoionization quantum yields. A convenient 147 nm actinometer
- 15 February 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 62 (4) , 1469-1472
- https://doi.org/10.1063/1.430607
Abstract
The photoionization quantum yields of trimethylamine, triethylamine, dipropylamine, di−iso−propylamine, and tetramethylene sulfide have been determined, at 147 nm, to be 0.38, 0.46, 0.096, 0.15, and 0.10, respectively. These ionization efficiences permit actinometry based upon saturation current measurements. This physical technique of absolute photon flux measurement is contrasted with the chemical actinometers currently in use at 147 nm.Keywords
This publication has 13 references indexed in Scilit:
- Ionization quantum yields and absorption coefficients of selected compounds at 58.4 and 73.6-74.4 nmJournal of Research of the National Bureau of Standards Section A: Physics and Chemistry, 1971
- The photolysis of N2O at 1470 ÅInternational Journal of Chemical Kinetics, 1971
- Photolysis of Hexafluoroacetone at 1470 Å. A Convenient Vacuum-Ultraviolet Chemical ActinometerThe Journal of Chemical Physics, 1970
- Far ultraviolet photolysis of carbon dioxideCanadian Journal of Chemistry, 1968
- Photolysis of Nitrous Oxide at 1470 ÅThe Journal of Chemical Physics, 1967
- Vacuum Ultraviolet PhotochemistryPublished by Wiley ,1964
- Photolysis of Nitrous Oxide. II. 1470 and 1830 AThe Journal of Chemical Physics, 1962
- Photolysis of Carbon DioxideThe Journal of Chemical Physics, 1960
- The photolysis of nitrous oxide in the far ultravioletPlanetary and Space Science, 1959
- Vacuum Ultraviolet Photochemistry, Part I. Nitrous Oxide at 1470 AThe Journal of Chemical Physics, 1954