Stimulated nuclear polarization - a new method for studying the mechanisms of photochemical reactions
- 1 January 1990
- journal article
- Published by Walter de Gruyter GmbH in Pure and Applied Chemistry
- Vol. 62 (8) , 1547-1556
- https://doi.org/10.1351/pac199062081547
Abstract
This report concerns a fundamentally new high-sensitive magnetic resonance method for detection of short-lived species - radical pairs, radical ion pairs, biradicals and radicals - the method of stimulated nuclear polarization (SNP). The SNP-method is based on the resonance mw-field effects on nuclear polarization in the products of the radical reactions. Using this method one can obtain information on the ESR spectrum of intermediate short-lived RP and on the channels of reaction product format ion.Keywords
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