Stimulated nuclear polarization - a new method for studying the mechanisms of photochemical reactions

Abstract
This report concerns a fundamentally new high-sensitive magnetic resonance method for detection of short-lived species - radical pairs, radical ion pairs, biradicals and radicals - the method of stimulated nuclear polarization (SNP). The SNP-method is based on the resonance mw-field effects on nuclear polarization in the products of the radical reactions. Using this method one can obtain information on the ESR spectrum of intermediate short-lived RP and on the channels of reaction product format ion.

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