Olefin Polymerization with Homogeneous Ziegler−Natta Catalysts: A DFT Quantum-Mechanical Study of the Reactions of Cp2MtCH3Cl Complexes (Mt = Ti, Zr) with Al(CH3)3 and MAO
- 1 December 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Macromolecules
- Vol. 30 (25) , 7673-7685
- https://doi.org/10.1021/ma9708611
Abstract
No abstract availableThis publication has 50 references indexed in Scilit:
- Ethylene polymerization with homogeneous Ziegler‐Natta catalysts: theoretical study on the role of ion pairs in the polymerization mechanismMacromolecular Rapid Communications, 1997
- Modelling of ethylene polymerization with Cp2ZrCl2MAO catalystPolymer, 1994
- A Density Functional Study of Chain Growing and Chain Terminating Steps in Olefin Polymerization by Metallocene and Constrained Geometry CatalystsOrganometallics, 1994
- NMR study of the reactions in Cp2TiMeCl/AlMe3 and Cp2TiMeCl/methylalumoxane systems, catalysts for olefin polymerizationMacromolecular Rapid Communications, 1994
- An ab initio MO and MM study of homogeneous olefin polymerization with silylene-bridged zirconocene catalyst and its regio- and stereoselectivityJournal of the American Chemical Society, 1992
- An investigation of the reaction of bis(cyclopentadienyl)titanium dichlorides with trimethylaluminum. Mechanism of an .alpha.-hydrogen abstraction reactionOrganometallics, 1984
- The crystal and molecular structures of bent bis-π-cyclopentadienyl–metal complexes: (a) bis-π-cyclopentadienyldibromorhenium(V) tetrafluoroborate, (b) bis-π-cyclopentadienyldichloromolybdenum(IV), (c) bis-π-cyclopentadienylhydroxomethylaminomolybdenum(IV) hexafluorophosphate, (d) bis-π-cyclopentadienylethylchloromolybdenum(IV), (e) bis-π-cyclopentadienyldichloroniobium(IV), (f) bis-π-cyclopentadienyldichloromolybdenum(V) tetrafluoroborate, (g) μ-oxo-bis[bis-π-cyclopentadienylchloroniobium(IV)] tetrafluoroborate, (h) bis-π-cyclopentadienyldichlorozirconiumActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1974
- The Monomer—Dimer Equilibria of liquid Aluminum Alkyls : V. Tri-n-Propylaluminum, Tri-n-Butylaluminum and Tri-n-Octylaluminum: The effect of chain length on the equilibriaJournal of Organometallic Chemistry, 1974
- BIS-(CYCLOPENTADIENYL)-TITANIUM DICHLORIDE —ALKYLALUMINUM COMPLEXLS AS CATALYSTS FOR THE POLYMERIZATION OF ETHYLENEJournal of the American Chemical Society, 1957
- A CRYSTALLIZABLE ORGANOMETALLIC COMPLEX CONTAINING TITANIUM AND ALUMINUMJournal of the American Chemical Society, 1957