Thermodynamic study of the binding of dibenzo-18-crown-6 with Ag+, Pb2+and Cd2+in acetonitrile–water solvents
- 1 January 1995
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions
- Vol. 91 (11) , 1607-1610
- https://doi.org/10.1039/ft9959101607
Abstract
Thermodynamic data for the binding of Ag+, Pb2+ and Cd2+ nitrates with dibenzo-18-crown-6 in acetonitrile–water solvents have been obtained in the temperature range 288–308 K using a conductometric technique. The observed molar conductivities, Λ, were found to decrease significantly for mole ratios less than unity. The conductivity data have been analysed using a model involving 1 : 1 stoichiometry. The stability constant, K, and the limiting molar conductivity, Λc, for each 1 : 1 complex have been obtained from the measured conductivities by using a non-linear least-squares curve-fitting procedure. The complexation sequence, based on the value of log K at 298 K, was found to be Pb2+ > Cd2+ > Ag+. The significance of the reported values of ΔH0 and ΔS0 in the present work has been discussed.Keywords
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