Liquid-phase Cu(acac)2/ZnEt2 syngas conversion catalysts: investigations by copper and zinc K-edge EXAFS
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 1027-1029
- https://doi.org/10.1039/c39940001027
Abstract
Cu K-edge EXAFS studies on syngas conversion catalysts, generated by the reaction of Cu(acac)2(acac = acetylacetonato) with ZnEt2 at room temp., reveal the presence small Cu metal particles (ca. 10–25 Å) in solution; Zn K-edge studies suggest the formation of oligomeric Zn species with oxygen present in the first coordination sphere.Keywords
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