Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(iii) ligands in supercritical CO2 and CH2Cl2This work was presented at the Green Solvents for Catalysis Meeting held in Bruchsal, Germany, 13–16th October 2002.
- 27 March 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Green Chemistry
- Vol. 5 (2) , 118-122
- https://doi.org/10.1039/b212313b
Abstract
Four chiral perfluoroalkylated monodentate phosphorus(III) ligands have been prepared and characterised. These ligands have been evaluated in the rhodium-catalysed asymmetric hydrogenation of dimethyl itaconate in both dichloromethane and supercritical CO2 (scCO2) and compared with the parent, non-perfluoroalkylated, catalyst systems.Keywords
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