Gas-Phase Electron Resonance Spectra of SF and SeF

15 March 1969

journal article
research article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 50 (6) , 2726-2732
https://doi.org/10.1063/1.1671436

Abstract

The electron resonance spectra of the gaseous radicals SF and SeF have been detected and analyzed. The derivation of an effective Hamiltonian which operates in the rotational subspace of the ground vibronic state is described. Use of this Hamiltonian yields the rotational constants, the fine‐structure splittings, and the axial components of the ¹⁹F hyperfine interaction for both radicals.

Keywords

FINE STRUCTURE

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