Primary photoproducts of furan-2-carbonitrile and N-methylpyrrole-2-carbonitrile: trapping by methanol addition
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 24,p. 1610-1611
- https://doi.org/10.1039/c29710001610
Abstract
Irradiation of furan-2-carbonitrile and of N-methylpyrrole-2-carbonitrile in methanol yielded, respectively, trans-3-formly-2-methoxycyclopropane-1-carbonitrile and N-methyl-3-methoxy-5-azabicyclo[2,1,0]pentane-1-carbonitrile as primary photoproducts, indicating as intermediate species a cyclopropenecarboxaldehyde for furan and an azabicyclopentene for pyrrole.Keywords
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