Stereoselective exocyclic double bond formation via vinyl radical cyclization
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 480-482
- https://doi.org/10.1039/c39890000480
Abstract
A stereoselective route to 2,6-cis-disubstituted 4-methoxycarbonylmethylenetetrahydropyrans has been developed which uses a vinyl radical cyclization to establish the geometry of the exocyclic double bond.Keywords
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