Studies of ansa-bis(cyclopentadienyl)tungsten derivatives
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 16,p. 2689-2696
- https://doi.org/10.1039/a803076f
Abstract
The new compounds [W{(η-C5H4)X(η-C5H4)}Cl2] 1, [W{(η-C5H4)X(η-C5H4)}Me2] 2, [W{(η-C5H4)SiMe2(η-C5H4)}(SPh)2] 3, [W{(η-C5H4)X(η-C5H4)}H(Cl)] 4, [W{(η-C5H4)X(η-C5H4)}H2] 5 and [W{(η-C5H4)X(η-C5H4)}H3]+Y– 6, where X = SiMe2, SiEt2 or CMe2CMe2, and Y = BF4 or Cl, have been prepared. The crystal structures of [W{(η-C5H4)X(η-C5H4)}Me2] (X = SiMe2 or CMe2CMe2) have been determined.Keywords
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