Kinetics of reaction of peroxodisulphate with the 5-nitro-, 3-sulphonato- and 5-sulphonato-substituted derivatives of the tris-(1,10-phenanthroline)iron(II) cation in aqueous solution
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2111-2113
- https://doi.org/10.1039/j19700002111
Abstract
The kinetics of reaction of peroxodisulphate with substituted tris-(1,10-phenanthroline)iron(II) complexes in aqueous solution have been further investigated. For complexes containing strongly electron-withdrawing nitro- or sulphonato-substituents, reaction proceeds by paralled oxidation and aquation rate-determining steps, whereas for other complexes oxidation is the dominant process.Keywords
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