Die Addition von Fluorcarbenen an Norbornadien: Eine Homo‐1,4‐addition
- 1 January 1974
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 57 (1) , 104-113
- https://doi.org/10.1002/hlca.19740570110
Abstract
It has been found that difluorocarbene undergoes extensive addition to the endo‐face of norbornadiene, yeilding the cheletropic adduct, 4.4‐difluorotetracyclo[3.3.0.02,8.03,6]‐octane. Similar behaviour has been observed for fluorochlorocarbene. Possible mechanisms to rationalize this novel behaviour of carbenes are discussed.Keywords
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