Synthesis of Mono- and Sesquiterpenoids; XXII.1Synthesis of (+)-Pinthunamide, a Sesquiterpene Metabolite of a Fungus,Ampulliferinasp.
- 1 January 1993
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1993 (04) , 406-410
- https://doi.org/10.1055/s-1993-25873
Abstract
Pinthunamide (1), a sesquiterpene metabolite produced by a fungus Ampulliferina sp., was synthesized by starting from (1R,4S,6S)-6-hydroxy-1-methylbicyclo[2.2.2]octan-2-one (4), which could readily be prepared by yeast reduction of the corresponding ß-diketone 5.Keywords
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