Direct Zn–diamine promoted reduction of CO and CN bonds by polymethylhydrosiloxane in methanol
- 20 December 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 3,p. 332-333
- https://doi.org/10.1039/b210144k
Abstract
Ketones and imines are chemoselectively reduced at room temperature in methanol to the corresponding alcohols and amines in high yields in a one-step procedure using polymethylhydrosiloxane (PMHS) and a simple zinc–diamine catalyst.Keywords
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