Facile Synthesis of Alkynyl− and Vinylidene−Niobocene Complexes. Unexpected η¹-Vinylidene−η²-Alkyne Isomerization

This publication has 79 references indexed in Scilit:

• A Cationic Imido Complex of Permethyltantalocene: H₂ and Carbon−Hydrogen Bond Activation, [2 + 2] Cycloaddition Reactions, and an Unusual Reaction with Carbon Dioxide That Affords Coordinated Isocyanate
  Organometallics, 1998
• Using redundant internal coordinates to optimize equilibrium geometries and transition states
  Journal of Computational Chemistry, 1996
• Rearrangement, hydride abstraction, and retro ene reactions of dicarbonyl(.eta.5-cyclopentadienyl)iron vinylidene triflates
  Organometallics, 1992
• Metal-hydride alkynyl .fwdarw. metal-vinylidene rearrangements occurring in both solid state and solution. Role of the 1-alkyne substituent in determining the relative stability of .pi.-alkyne, hydride alkynyl, and vinylidene forms at cobalt
  Organometallics, 1991
• Early-transition-metal ketenimine complexes. Synthesis, reactivity and structural characterization of complexes with .eta.2(C,N)-ketenimine groups bound to the halobis[(trimethylsilyl)cyclopentadienyl]niobium unit. X-ray structure of Nb(.eta.5-C5H4SiMe3)2Cl(.eta.2(C,N)-PhN:C:CPh2)
  Organometallics, 1990
• A study of the singlet and triplet states of vinylidene by photoelectron spectroscopy of H2C=C−, D2C=C−, and HDC=C−. Vinylidene–acetylene isomerization
  The Journal of Chemical Physics, 1989
• Photoassisted polymerization of terminal alkynes by W(CO)6 involving catalyst generation by an alkyne to vinylidene ligand rearrangement
  Journal of the American Chemical Society, 1985
• Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals
  The Journal of Chemical Physics, 1985
• Preparation of the paramagnetic alkyls bis(cyclopentadienyl)dimethylniobium and bis(methylcyclopentadienyl)dimethyltantalum and some six- and eight-coordinate phosphine derivatives of niobium(IV)
  Inorganic Chemistry, 1977
• Structure and chemistry of bis(cyclopentadienyl)-MLn complexes
  Journal of the American Chemical Society, 1976