A Novel Perfluoroalkylation of Pyrroles with Perfluoroalkanesulfonyl chloride Catalyzed by a Ruthenium(II) Phosphine Complex
- 1 July 1994
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 24 (14) , 2049-2055
- https://doi.org/10.1080/00397919408010214
Abstract
Direct perfluoroalkylation of N-substituted pyrroles with tridecafluorohexanesulfonyl chloride catalyzed by a ruthenium(II) phosphine complex proceeds regioselectively in high yield.Keywords
This publication has 19 references indexed in Scilit:
- Recent Advances in Trifluoromethylation.Journal of Synthetic Organic Chemistry, Japan, 1991
- Perfluoroalkylations of nitrogen-containing heteroaromatic compounds with bis(perfluoroalkanoyl) peroxidesJournal of the Chemical Society, Perkin Transactions 1, 1989
- Direct perfluoroalkylation including trifluoromethylation of aromatics with perfluoro carboxylic acids mediated by xenon difluorideThe Journal of Organic Chemistry, 1988
- Tetrahedron report number 221Tetrahedron, 1987
- Pregeneration, spectroscopic detection and chemical reactivity of (trifluoromethyl)copper, an elusive and complex speciesJournal of the American Chemical Society, 1986
- Synthesis and Reactivity of N-Trifluoromethyl-N-nitrosotrifluoromethanesulfonamide as a New Type of Trifluoromethylating AgentBulletin of the Chemical Society of Japan, 1986
- Perfluoropropylation of aromatic compounds with bis(heptafluorobutyryl) peroxideJournal of the Chemical Society, Chemical Communications, 1985
- Transition-metal complex catalyzed polyfluoroalkylation. I. Facile addition of polyfluoroalkyl halides to carbon-carbon multiple bondsTetrahedron Letters, 1984
- Improved deprotection in solid phase peptide synthesis: quantitative reduction of methionine sulfoxide to methionine during HF cleavageTetrahedron Letters, 1982
- PERFLUOROALKYLATION OF AROMATIC COMPOUNDS WITH RfI(Ph)OSO2CF3Chemistry Letters, 1981