A novel synthesis of pyrrolizidine alkaloids by means of an intramolecular carbenoid displacement (ICD) reaction
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 4,p. 833-837
- https://doi.org/10.1039/p19880000833
Abstract
The pyrrolizidine alkaloids, (±)-trachelanthamidine, (±)isoretronecanol, and (±)-supinidine were synthesized by using an intramolecular carbenoid displacement (ICD) reaction of the diazo-sulphide or the diazo-selenide derivatives as a key step.This publication has 2 references indexed in Scilit:
- Pyrrolizidinone and indolizidinone synthesis: generation and intramolecular addition of .alpha.-acylamino radicals to olefins and allenesJournal of the American Chemical Society, 1984
- A short and stereoselective synthesis of the carbapenem antibiotic PS-5Journal of the Chemical Society, Perkin Transactions 1, 1981